Issue 31, 2010
From the journal:

Physical Chemistry Chemical Physics

Hydrophilicity, the major determining factor influencing the solvation environment of protic ionic liquids

Lawrence Wright,a   Marc W. Sanders,a   Lauren Tate,b   Gayle Fairless,b   Lorna Crowhurst,b   Neil C. Bruce,c   Adam J. Walker,*b   Guy A. Hemburyb  and  Seishi Shimizu*a  

* Corresponding authors

a York Structural Biology Laboratory, Department of Chemistry, University of York, Heslington, UK
E-mail: shimizu@ysbl.york.ac.uk
Fax: +44 1904 328266
Tel: +44 1904 328281

b Bioniqs Ltd., Biocentre, York Science Park
E-mail: adam.walker@bioniqs.com
Tel: +44 1904 561538

c CNAP, Department of Biology, University of York, Heslington

Abstract

The study of solubility of 4-nitroaniline and its N,N-diethyl derivative in ionic liquids (ILs) of varying water content has shown that it is the interaction between water and the ILs’ ions, and not with the solute, that is the most important factor determining the solute's preferential hydration parameter and thus the solvation shell structure.

Graphical abstract: Hydrophilicity, the major determining factor influencing the solvation environment of protic ionic liquids

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Article information

DOI
https://doi.org/10.1039/B919348K
Article type
Paper
Submitted
16 Sep 2009
Accepted
29 Apr 2010
First published
18 Jun 2010

Phys. Chem. Chem. Phys., 2010,12, 9063-9066

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Hydrophilicity, the major determining factor influencing the solvation environment of protic ionic liquids

L. Wright, M. W. Sanders, L. Tate, G. Fairless, L. Crowhurst, N. C. Bruce, A. J. Walker, G. A. Hembury and S. Shimizu, Phys. Chem. Chem. Phys., 2010, 12, 9063 DOI: 10.1039/B919348K

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