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Issue 10, 2010
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Mixed-valent vanadium substituted polyoxometalates: the wheel shaped [Rb3⊂{VVVIV3O7(H2O)6}2{H6P6W39O147(H2O)3}]15−

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Abstract

The wheel shaped polyoxoanion [Rb3{VVVIV3O7(H2O)6}2{H6P6W39O147(H2O)3}]15− comprising a macrocyclic tungstophosphate template wheel [P6W39O147(H2O)3]30− ({P6W39}) capped by two unprecedented mixed-valent oxovanadium {(VV[double bond, length as m-dash]O)(VIV[double bond, length as m-dash]O)32-O)3(H2O)6}3+ groups has been prepared and characterized by X-ray diffraction, elemental analysis, TGA, IR and 31P NMR spectroscopy. The title polyanion represents the first example of the {P6W39} unit stabilizing a polynuclear metal assembly.

Graphical abstract: Mixed-valent vanadium substituted polyoxometalates: the wheel shaped [Rb3⊂{VVVIV3O7(H2O)6}2{H6P6W39O147(H2O)3}]15−

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Supplementary files

Article information


Submitted
07 Apr 2010
Accepted
12 May 2010
First published
27 May 2010

CrystEngComm, 2010,12, 2684-2686
Article type
Communication

Mixed-valent vanadium substituted polyoxometalates: the wheel shaped [Rb3⊂{VVVIV3O7(H2O)6}2{H6P6W39O147(H2O)3}]15−

A. S. Assran, N. V. Izarova and U. Kortz, CrystEngComm, 2010, 12, 2684 DOI: 10.1039/C0CE00068J

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