Issue 10, 2010
From the journal:

CrystEngComm

A layered coordination polymer based on an azodibenzoate linker connected to aluminium (MIL-129)†

Christophe Volkringer,a   Thierry Loiseau,‡*a   Thomas Devic,a   Gérard Férey,a   Dmitry Popov,b   M. Burghammerb  and  C. Riekelb  

* Corresponding authors

a Institut Lavoisier (UMR CNRS 8180), Institut Universitaire de France, Porous Solids Group, Université de Versailles Saint Quentin en Yvelines, 45, avenue des Etats-Unis, Versailles, France
E-mail: thierry.loiseau@ensc-lille.fr
Fax: (+33) 3 20 43 68 14
Tel: (+33) 3 20 43 44 34

b ESRF, 6, rue Jules Horowitz, B. P. 220, Grenoble cedex, France

Abstract

A layered aluminium carboxylate containing the 4,4′-azobenzenedicarboxylate anion (MIL-129) has been hydrothermally synthesized (210 °C, 24 h). Its crystal structure was determined by means of microdiffraction technique using synchrotron radiation. It consists of infinite trans-connected chains of aluminium-centered octahedra, linked to each other through the organic molecules, in order to generate infinite sheets, containing double stacking of organic species. The cohesion of the structure is ensured by the close packing due to π–π interactions between aromatic rings of the ligands and no porosity is observed.

Graphical abstract: A layered coordination polymer based on an azodibenzoate linker connected to aluminium (MIL-129)

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Article information

DOI
https://doi.org/10.1039/C002214D
Article type
Paper
Submitted
02 Feb 2010
Accepted
17 Apr 2010
First published
22 Jun 2010

CrystEngComm, 2010,12, 3225-3228

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A layered coordination polymer based on an azodibenzoate linker connected to aluminium (MIL-129)

C. Volkringer, T. Loiseau, T. Devic, G. Férey, D. Popov, M. Burghammer and C. Riekel, CrystEngComm, 2010, 12, 3225 DOI: 10.1039/C002214D

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