Issue 2, 2010
From the journal:

CrystEngComm

pH-dependent assembly of a series of inorganic–organic hybrid molybdenum(v) phosphate†

Xiao Zhang,ac   Zhihui Yi,bc   Liyan Zhao,a   Qian Chen,a   Xiaolin Wang,a   Jiqing Xu,c   Wujiong Xia*a  and  Chao Yanga  

* Corresponding authors

a State Key Lab of Urban Water Resource and Environment (SKLUWRE), National Engineering Research Center of Urban Water Resource & Academy of Fundamental and Interdisciplinary Science, Harbin Institute of Technology, Harbin, Heilongjiang, P. R. China
E-mail: zhangx@hit.edu.cn, xiawj@hit.edu.cn
Fax: +086-45186403193
Tel: +086-45186403193

b State Key Laboratory of Polymer Physics and Chemistry, Changchun, Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R China

c College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin, P. R. China

Abstract

Four inorganic–organic hybrid materials based on poly(oxomolybdophosphate) cluster building blocks have been obtained by hydrothermal methods. 1 shows a 2-D sheet structure, 2 and 3 possess 1-D chain structures and 4 is the discrete cluster. Crystal structural analysis reveals that the dimensionality and organization of those compounds can be tuned by the pH value of the reaction system. In addition, the fluorescence emissions are analysed of compounds 1, 2 and 4 containing Cd atoms with d10 electronic configuration red-shift along with the increase in the dimensions of those compounds.

Graphical abstract: pH-dependent assembly of a series of inorganic–organic hybrid molybdenum(v) phosphate

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Article information

DOI
https://doi.org/10.1039/B917754J
Article type
Paper
Submitted
27 Aug 2009
Accepted
23 Sep 2009
First published
05 Oct 2009

CrystEngComm, 2010,12, 595-603

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pH-dependent assembly of a series of inorganic–organic hybrid molybdenum(V) phosphate

X. Zhang, Z. Yi, L. Zhao, Q. Chen, X. Wang, J. Xu, W. Xia and C. Yang, CrystEngComm, 2010, 12, 595 DOI: 10.1039/B917754J

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