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Issue 47, 2010
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Highly charged supramolecular oligomers based on the dimerization of corannulene tetraanion

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Abstract

The supramolecular dimerization of tetraanionic corannulene is utilized as a self-assembly motif for the construction of highly charged, buckybowl-based supramolecular oligomers. Oligomers of up to 7 units (3900 g mol−1) of reduced dicorannulenic monomers are identified and characterized by various NMR techniques, and the reversibility of their assembly is established through the concentration dependence of their molecular weight and the effect of monofunctional chain-stoppers.

Graphical abstract: Highly charged supramolecular oligomers based on the dimerization of corannulene tetraanion

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Publication details

The article was received on 20 Sep 2010, accepted on 20 Oct 2010 and first published on 05 Nov 2010


Article type: Communication
DOI: 10.1039/C0CC03965A
Citation: Chem. Commun., 2010,46, 9010-9012
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    Highly charged supramolecular oligomers based on the dimerization of corannulene tetraanion

    D. Eisenberg, J. M. Quimby, E. A. Jackson, L. T. Scott and R. Shenhar, Chem. Commun., 2010, 46, 9010
    DOI: 10.1039/C0CC03965A

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