Issue 42, 2010

Chain mechanism for exchange of D2 with a ruthenium hydride

Abstract

The ruthenium hydride of (Ar4CpOH)Ru(CO)2H exchanges cleanly and rapidly with D2 at room temperature to generate the ruthenium deuteride. A chain mechanism is proposed to explain the much more rapid exchange of RuH/D2 than RuCO exchange with 13CO.

Graphical abstract: Chain mechanism for exchange of D2 with a ruthenium hydride

  • This article is part of the themed collection: Hydrogen

Supplementary files

Article information

Article type
Communication
Submitted
28 Jul 2010
Accepted
01 Sep 2010
First published
21 Sep 2010

Chem. Commun., 2010,46, 7915-7917

Chain mechanism for exchange of D2 with a ruthenium hydride

C. P. Casey, J. B. Johnson, X. Jiao, S. E. Beetner and S. W. Singer, Chem. Commun., 2010, 46, 7915 DOI: 10.1039/C0CC02875D

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