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Issue 44, 2010
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Highly stable 7-N,N-dibutylamino-2-azaphenanthrene and 8-N,N-dibutylamino-2-azachrysene as a new class of second order NLO-active chromophores

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Abstract

7-N,N-Dibutylamino-2-azaphenanthrene (L3), 8-N,N-dibutylamino-2-azachrysene (L4) and related Ir(I) complexes or alkylated salts show high second-order NLO responses, as determined by the EFISH technique and DFT calculations. L4 is appealing as building block for NLO active materials due to its unexpected large μβ1.907value and its very high thermal stability.

Graphical abstract: Highly stable 7-N,N-dibutylamino-2-azaphenanthrene and 8-N,N-dibutylamino-2-azachrysene as a new class of second order NLO-active chromophores

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Publication details

The article was received on 24 Jul 2010, accepted on 09 Sep 2010 and first published on 05 Oct 2010


Article type: Communication
DOI: 10.1039/C0CC02781B
Citation: Chem. Commun., 2010,46, 8374-8376
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    Highly stable 7-N,N-dibutylamino-2-azaphenanthrene and 8-N,N-dibutylamino-2-azachrysene as a new class of second order NLO-active chromophores

    V. Calabrese, S. Quici, E. Rossi, E. Cariati, C. Dragonetti, D. Roberto, E. Tordin, F. De Angelis and S. Fantacci, Chem. Commun., 2010, 46, 8374
    DOI: 10.1039/C0CC02781B

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