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Issue 42, 2010
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Azulene based metal–organic frameworks for strong adsorption of H2†‡

Samir Barman,a   Hiroyasu Furukawa,*b   Olivier Blacque,a   Koushik Venkatesan,a   Omar M. Yaghib  and  Heinz Berke*a  
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* Corresponding authors

a Department of Inorganic Chemistry, University of Zürich, Winterthurerstrasse 190, Zürich, Switzerland
E-mail: hberke@aci.uzh.ch
Fax: (+41) 44-635-6802

b Center for Reticular Chemistry, Department of Chemistry and Biochemistry, University of California-Los Angeles, 607 Charles E. Young Drive East, Los Angeles, California 90095, USA
E-mail: furukawa@chem.ucla.edu

Abstract

Two Zn MOFs, MOF-645 and MOF-646, comprised of polarized 1,3-azulenedicarboxylate were synthesized. The guest free MOF-646 showed strong MOF-H2 interactions (7.8–6.8 kJ mol−1), which revealed the significant impact of internally polarized azulene backbone to stabilized H2 molecules in the framework.

Graphical abstract: Azulene based metal–organic frameworks for strong adsorption of H2

  • This article is part of the themed collection: Hydrogen
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Article information

https://doi.org/10.1039/C0CC02589E
Submitted
15 Jul 2010
Accepted
03 Sep 2010
First published
27 Sep 2010
Chem. Commun., 2010,46, 7981-7983
Article type
Communication
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Azulene based metal–organic frameworks for strong adsorption of H2

S. Barman, H. Furukawa, O. Blacque, K. Venkatesan, O. M. Yaghi and H. Berke, Chem. Commun., 2010, 46, 7981
DOI: 10.1039/C0CC02589E

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