Dramatic micellar rate enhancement of the Cu2+ catalyzed vinologous Friedel–Crafts alkylation in water

Fiora Rosati; Jens Oelerich; Gerard Roelfes

doi:10.1039/C0CC02584D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Dramatic micellar rate enhancement of the Cu²⁺ catalyzed vinologous Friedel–Crafts alkylation in water†

Fiora Rosati,^a Jens Oelerich^a and Gerard Roelfes*^a

Author affiliations

* Corresponding authors

^a Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, Groningen, The Netherlands
E-mail: J.G.Roelfes@rug.nl

Abstract

A dramatic rate enhancement of the Cu²⁺ catalyzed Friedel–Crafts alkylation in water was achieved in the presence of sodium dodecyl sulfate (SDS) micelles.

Download options Please wait...

Supplementary files

Experimental procedures of the catalytic experiments and kinetic experiments, cmc measurement, UV spectra of the substrate 1a bound to Cu(NO ₃) ₂ in the presence and in the absence of surfactant and ¹H-NMR spectra of the Friedel–Crafts products. PDF (544K)

Article information

DOI: https://doi.org/10.1039/C0CC02584D
Article type: Communication
Submitted: 15 Jul 2010
Accepted: 23 Aug 2010
First published: 08 Sep 2010

Download Citation

Chem. Commun., 2010,46, 7804-7806

Permissions

Request permissions

Dramatic micellar rate enhancement of the Cu²⁺ catalyzed vinologous Friedel–Crafts alkylation in water

F. Rosati, J. Oelerich and G. Roelfes, Chem. Commun., 2010, 46, 7804 DOI: 10.1039/C0CC02584D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications