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Supramolecular photosynthetic systems made up of the [Ir(ppy)2(bpy)]+ and [Co(bpy)3]2+ cores (ppy = 2-phenylpyridinate, bpy = 2,2′-bipyridine) are in situ self-assembled in aqueous media to generate H2 upon visible light irradiation, where one of them recorded a relatively high turnover number of 20.

Graphical abstract: Photocatalytic hydrogen production from water in self-assembled supramolecular iridium–cobalt systems

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