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Issue 36, 2010
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A divergent synthesis of modular dendrimersvia sequential C–C bond fragmentation thio-Michael addition

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Abstract

The C–C bond fragmentation of carbocycles has been developed as a new method for the divergent synthesis of dendrimers. The scope of this reaction was examined with the preparation of six first generation dendrimers from structurally diverse and readily available fragmentation precursors. By pairing the fragmentation with a thio-Michael reaction, the preparation of a [G4]-ene24 dendrimer has been achieved.

Graphical abstract: A divergent synthesis of modular dendrimers via sequential C–C bond fragmentation thio-Michael addition

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Article information


Submitted
01 Jul 2010
Accepted
28 Jul 2010
First published
23 Aug 2010

Chem. Commun., 2010,46, 6789-6791
Article type
Communication

A divergent synthesis of modular dendrimers via sequential C–C bond fragmentation thio-Michael addition

J. Hierold, A. Gray-Weale and D. W. Lupton, Chem. Commun., 2010, 46, 6789
DOI: 10.1039/C0CC02289F

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