Issue 35, 2010
From the journal:

Chemical Communications

Unexpected fluorescence properties in an axially σ-bonded ferrocenyl-containing porphyrin†

Pavlo V. Solntsev,a   Jared R. Sabin,a   Samantha J. Dammer,a   Nikolay N. Gerasimchukb  and  Victor N. Nemykin*a  

* Corresponding authors

a Department of Chemistry & Biochemistry, 1039 University Drive, University of Minnesota Duluth, Duluth, USA
E-mail: vnemykin@d.umn.edu
Fax: 1 218 726 7394
Tel: 1 218 726 6729

b Department of Chemistry, Missouri State University, 901 South National Avenue, Springfield, USA

Abstract

Molecular structure, redox, and unexpected fluorescence properties of a tetraphenylporphyrin tin(IV) complex axially σ-bonded with two ferrocene substituents were investigated using UV-vis, MCD, electro- and spectroelectrochemical methods as well as DFT calculations and X-ray crystallography.

Graphical abstract: Unexpected fluorescence properties in an axially σ-bonded ferrocenyl-containing porphyrin

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Article information

DOI
https://doi.org/10.1039/C0CC02171G
Article type
Communication
Submitted
29 Jun 2010
Accepted
26 Jul 2010
First published
16 Aug 2010

Chem. Commun., 2010,46, 6581-6583

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Unexpected fluorescence properties in an axially σ-bonded ferrocenyl-containing porphyrin

P. V. Solntsev, J. R. Sabin, S. J. Dammer, N. N. Gerasimchuk and V. N. Nemykin, Chem. Commun., 2010, 46, 6581 DOI: 10.1039/C0CC02171G

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