Issue 41, 2010

Electronic effects in iridium C–H borylations: insights from unencumbered substrates and variation of boryl ligand substituents

Abstract

Experiment and theory favour a model of C–H borylation where significant proton transfer character exists in the transition state.

Graphical abstract: Electronic effects in iridium C–H borylations: insights from unencumbered substrates and variation of boryl ligand substituents

Supplementary files

Article information

Article type
Communication
Submitted
23 Jun 2010
Accepted
24 Aug 2010
First published
20 Sep 2010

Chem. Commun., 2010,46, 7724-7726

Electronic effects in iridium C–H borylations: insights from unencumbered substrates and variation of boryl ligand substituents

B. A. Vanchura, II, S. M. Preshlock, P. C. Roosen, V. A. Kallepalli, R. J. Staples, R. E. Maleczka, Jr., D. A. Singleton and M. R. Smith, III, Chem. Commun., 2010, 46, 7724 DOI: 10.1039/C0CC02041A

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