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Issue 37, 2010
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New azaborine-thiophene heteroacenes

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A new class of heteroacenes containing B, N and S elements in the 22-electron aromatic nucleus has been synthesized by reaction of diaminoterthiophenes with dichlorophenylborane. Their structure was studied by X-ray crystallography and DFT calculations. UV-Vis absorption /emission spectroscopy shows high rigidity and deep-blue fluorescence of these compounds.

Graphical abstract: New azaborine-thiophene heteroacenes

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The article was received on 18 Jun 2010, accepted on 10 Aug 2010 and first published on 23 Aug 2010

Article type: Communication
DOI: 10.1039/C0CC01963A
Chem. Commun., 2010,46, 7007-7009

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    New azaborine-thiophene heteroacenes

    M. Lepeltier, O. Lukoyanova, A. Jacobson, S. Jeeva and D. F. Perepichka, Chem. Commun., 2010, 46, 7007
    DOI: 10.1039/C0CC01963A

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