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Abstract | Cited by

Complex (Cp)(ArN[double bond, length as m-dash])Mo(H)(PMe3) (2, Ar = 2,6-diisopropylphenyl) catalyzes the hydrosilylation of carbonyls by an unexpected associative mechanism. Complex 2 also reacts with PhSiH3 by a σ-bond metathesis mechanism to give the silyl derivative (Cp)(ArN[double bond, length as m-dash])Mo(SiH2Ph)(PMe3).

Graphical abstract: The unexpected mechanism of carbonyl hydrosilylation catalyzed by (Cp)(ArN [[double bond, length as m-dash]] )Mo(H)(PMe3)

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