Issue 43, 2010
From the journal:

Chemical Communications

Spontaneous resolution upon crystallization of chiral La(iii) and Gd(iii) MOFs from achiral dihydroxymalonate†

Beatriz Gil-Hernández,a   Henning A. Höppe,b   Jana K. Vieth,b   Joaquin Sanchiz*a  and  Christoph Janiak*b  

* Corresponding authors

a Departamento de Química Inorgánica, Universidad de La Laguna, La Laguna 38206, Spain
E-mail: jsanchiz@ull.es
Fax: +34 922318461
Tel: +34 922316502 ext 5425

b Institut für Anorganische und Analytische Chemie, Universität Freiburg, Albertstr. 21, 79104 Freiburg, Germany
E-mail: janiak@uni-freiburg.de
Tel: +49 761 2036127

Abstract

The achiral chelating and bridging dihydroxymalonato (mesoxalato) ligand is a new enantiopurity enforcer in extended structures by yielding the Λ/Δ-metal configured homochiral MOFs 2D-[Ln2(μ-mesoxalato)3(H2O)6] (Ln = La(III), Gd(III)) through self-resolution during crystal growth.

Graphical abstract: Spontaneous resolution upon crystallization of chiral La(iii) and Gd(iii) MOFs from achiral dihydroxymalonate

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Article information

DOI
https://doi.org/10.1039/C0CC01804J
Article type
Communication
Submitted
09 Jun 2010
Accepted
10 Sep 2010
First published
29 Sep 2010

Chem. Commun., 2010,46, 8270-8272

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Spontaneous resolution upon crystallization of chiral La(III) and Gd(III) MOFs from achiral dihydroxymalonate

B. Gil-Hernández, H. A. Höppe, J. K. Vieth, J. Sanchiz and C. Janiak, Chem. Commun., 2010, 46, 8270 DOI: 10.1039/C0CC01804J

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