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Issue 36, 2010
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Catalytic intramolecular aromatic C–H alkenylation of arenes with non-activated ketones: synthesis of 4-alkylene quinolin-2-ones

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Abstract

The catalytic intramolecular aromatic C–H alkenylation of arenes with non-activated ketone carbonyls has been realized for the first time, leading to the synthesis of antiviral 4-alkylene quinolin-2-ones, where the quaternary carbon adjacent to the ketone carbonyl plays an essential role in this catalytic reaction.

Graphical abstract: Catalytic intramolecular aromatic C–H alkenylation of arenes with non-activated ketones: synthesis of 4-alkylene quinolin-2-ones

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Supplementary files

Article information


Submitted
05 Jun 2010
Accepted
28 Jul 2010
First published
25 Aug 2010

Chem. Commun., 2010,46, 6843-6845
Article type
Communication

Catalytic intramolecular aromatic C–H alkenylation of arenes with non-activated ketones: synthesis of 4-alkylene quinolin-2-ones

Y. Wang, W. Li, G. Che, X. Bi, P. Liao, Q. Zhang and Q. Liu, Chem. Commun., 2010, 46, 6843
DOI: 10.1039/C0CC01758B

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