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Structural characterization of a sulfate complex with an azamacrocycle suggests that one sulfate is encapsulated in the macrocyclic cavity with eight hydrogen bonds; a significant selectivity of the host was observed for sulfate over halides, nitrate and perchlorate as evaluated by 1H NMR studies in water.

Graphical abstract: Encapsulation and selective recognition of sulfate anion in an azamacrocycle in water

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