Issue 33, 2010

An extraordinary boron-mediated 16R-channel-containing trivalent vanadium phosphite with unique solid state redox properties

Abstract

For the first time, an open-framework oxysalt of trivalent vanadium is demonstrated, prepared from a single tetravalent vanadium source under acidic hydrothermal conditions. The borate-incorporated structure features intersecting 2D 16R channels and unusual solid-state redox properties confirmed by K-edge XANES, EPR spectral data and magnetic susceptibility measurements.

Graphical abstract: An extraordinary boron-mediated 16R-channel-containing trivalent vanadium phosphite with unique solid state redox properties

Supplementary files

Article information

Article type
Communication
Submitted
24 Apr 2010
Accepted
21 Jun 2010
First published
27 Jul 2010

Chem. Commun., 2010,46, 6141-6143

An extraordinary boron-mediated 16R-channel-containing trivalent vanadium phosphite with unique solid state redox properties

H. Huang and S. Wang, Chem. Commun., 2010, 46, 6141 DOI: 10.1039/C0CC01105C

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