Issue 24, 2010
From the journal:

Chemical Communications

Synthesis and structures of the homoleptic cations [M(PMe3)5]+ (M = Rh, Ir)†

Joseph H. Riversa  and  Richard A. Jones*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, Texas, USA
E-mail: rajones@mail.utexas.edu
Tel: +1 (512) 471-1706

Abstract

The homoleptic cations [M(PMe3)5]+ (M = Rh, Ir) are formed in high yield from reactions of 16 electron 4 coordinate precursors, such as [Rh(PMe3)4]+, with excess neat PMe3 at 80 °C.

Graphical abstract: Synthesis and structures of the homoleptic cations [M(PMe3)5]+ (M = Rh, Ir)

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Article information

DOI
https://doi.org/10.1039/C0CC00892C
Article type
Communication
Submitted
13 Apr 2010
Accepted
06 May 2010
First published
14 May 2010

Chem. Commun., 2010,46, 4300-4302

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Synthesis and structures of the homoleptic cations [M(PMe3)5]+ (M = Rh, Ir)

J. H. Rivers and R. A. Jones, Chem. Commun., 2010, 46, 4300 DOI: 10.1039/C0CC00892C

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