Issue 35, 2010
From the journal:

Chemical Communications

Effect of hydrophobic interaction cooperating with double Lewis acid activation in a zinc(ii) phosphodiesterase mimic†

Meng Zhao,a   Li Zhang,a   Huo-Yan Chen,a   Han-Lu Wang,a   Liang-Nian Jia  and  Zong-Wan Mao*a  

* Corresponding authors

a MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
E-mail: cesmzw@mail.sysu.edu.cn
Fax: +86-20-84112245
Tel: +86-20-84113788

Abstract

The novel dinuclear Zn(II) complex (1) containing a β-CD dimer could accelerate BNPP (a DNA substitute) hydrolysis more efficiently than catalyze HPNP (a RNA substitute) transesterification with different mechanisms involved; the β-CDs played remarkably different roles.

Graphical abstract: Effect of hydrophobic interaction cooperating with double Lewis acid activation in a zinc(ii) phosphodiesterase mimic

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0CC00838A
Article type
Communication
Submitted
09 Apr 2010
Accepted
15 Jul 2010
First published
09 Aug 2010

Chem. Commun., 2010,46, 6497-6499

Permissions

Request permissions

Effect of hydrophobic interaction cooperating with double Lewis acid activation in a zinc(II) phosphodiesterase mimic

M. Zhao, L. Zhang, H. Chen, H. Wang, L. Ji and Z. Mao, Chem. Commun., 2010, 46, 6497 DOI: 10.1039/C0CC00838A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements