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Issue 29, 2010
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Introduction of cavities up to 4 nm into a hierarchically-assembled metal–organic framework using an angular, tetratopic ligand

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Abstract

Cavities up to 4 nm have been introduced into a hierarchically-assembled metal–organic framework by adopting an angular, semi-flexible tetratopic ligand. The resulting MOF possesses permanent porosity and exhibits stepwise sorption isotherms for O2 and N2 gases.

Graphical abstract: Introduction of cavities up to 4 nm into a hierarchically-assembled metal–organic framework using an angular, tetratopic ligand

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Publication details

The article was received on 05 Apr 2010, accepted on 28 May 2010 and first published on 23 Jun 2010


Article type: Communication
DOI: 10.1039/C0CC00779J
Chem. Commun., 2010,46, 5223-5225

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    Introduction of cavities up to 4 nm into a hierarchically-assembled metal–organic framework using an angular, tetratopic ligand

    W. Zhuang, S. Ma, X. Wang, D. Yuan, J. Li, D. Zhao and H. Zhou, Chem. Commun., 2010, 46, 5223
    DOI: 10.1039/C0CC00779J

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