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Abstract | Cited by

The X-ray crystal structure of 1,12-dodecane diammonium (C12DA2+) encapsulated in cucurbit[8]uril reveals an unconventional U-shaped conformation of C12DA2+, which is attributed to the favorable host–guest interactions to overcome the charge–charge repulsion of the two ammonium groups in close proximity and high internal strain.

Graphical abstract: Unconventional U-shaped conformation of a bolaamphiphile embedded in a synthetic host

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