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The β-sheet self-assembly of an n-type NDI-dipeptide into a transparent, self-supporting hydrogel at low concentrations is described. The nanostructure of the gel is stabilized by the intermolecular π–π association of the NDI units and π–π interdigitation of the fluorene groups.

Graphical abstract: A π-conjugated hydrogel based on an Fmoc-dipeptide naphthalene diimide semiconductor

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