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Issue 28, 2010
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Dipyridyl β-diketonate complexes: versatile polydentate metalloligands for metal–organic frameworks and hydrogen-bonded networks

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Abstract

The Group 13 metal complexes [M(L2)3], where M is Al or Ga and L2 is 1,3-di(4-pyridyl)-1,3-propanedionato, are hexatopic metalloligands that have been used to prepare mixed-metal–organic frameworks containing interpenetrated primitive cubic networks. In contrast, the europium complex [Eu(HL2)3(H2L2)]Cl4·EtOH forms a hydrogen-bonded network following partial protonation of the pyridyl groups.

Graphical abstract: Dipyridyl β-diketonate complexes: versatile polydentate metalloligands for metal–organic frameworks and hydrogen-bonded networks

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Article information


Submitted
29 Mar 2010
Accepted
21 May 2010
First published
08 Jun 2010

Chem. Commun., 2010,46, 5067-5069
Article type
Communication

Dipyridyl β-diketonate complexes: versatile polydentate metalloligands for metal–organic frameworks and hydrogen-bonded networks

A. D. Burrows, C. G. Frost, M. F. Mahon, P. R. Raithby, C. L. Renouf, C. Richardson and A. J. Stevenson, Chem. Commun., 2010, 46, 5067 DOI: 10.1039/C0CC00646G

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