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Issue 42, 2010
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Oxidative addition of the bismuth-chloride bond: synthesis and structure of trans-[PtCl(PCy3)2{BiCl2}]

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Abstract

The synthesis and full characterisation of trans-[PtCl(PCy3)2{BiCl2}] is reported via the oxidative addition of the bismuth-chloride bond across [Pt(PCy3)2]; this represents the first instance of such an oxidative addition reaction to be undertaken by a bismuth halide bond.

Graphical abstract: Oxidative addition of the bismuth-chloride bond: synthesis and structure of trans-[PtCl(PCy3)2{BiCl2}]

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Publication details

The article was received on 29 Mar 2010, accepted on 11 Jun 2010 and first published on 30 Jun 2010


Article type: Communication
DOI: 10.1039/C0CC00639D
Citation: Chem. Commun., 2010,46, 7894-7896
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    Oxidative addition of the bismuth-chloride bond: synthesis and structure of trans-[PtCl(PCy3)2{BiCl2}]

    H. Braunschweig, P. Brenner, P. Cogswell, K. Kraft and K. Schwab, Chem. Commun., 2010, 46, 7894
    DOI: 10.1039/C0CC00639D

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