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Abstract | Cited by

Cationic rhodium(I) complexes containing the flexible hemilabile phosphine ligand (3-ethoxypropyl)diphenylphosphine efficiently catalyzed the anti-Markovnikov oxidative amination of styrene in tetrahydrofurane at 80 °C to produce (E)-1-styrylpiperidine with turnover frequencies up to 75 h−1 with excellent enamine selectivity (96%).

Graphical abstract: Rational design of efficient rhodium catalysts for the anti-markovnikov oxidative amination of styrene

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