Issue 22, 2010
From the journal:

Chemical Communications

Spin trapping of radical intermediates in gas phase catalysis: cyclohexaneoxidation over metal oxides†

Marco Contea  and  Victor Chechik*a  

* Corresponding authors

a Department of Chemistry, University of York, Heslington, York, UK
E-mail: vc4@york.ac.uk
Tel: +44 (0)1904 434185

Abstract

The formation of radicals in the gas phase oxidation of cyclohexane over metal oxides was studied using spin trapping and EPR spectroscopy; the results confirmed that during the catalytic initiation, the oxygen responsible for the radicals formation originates from the lattice of the metal oxide.

Graphical abstract: Spin trapping of radical intermediates in gas phase catalysis: cyclohexane oxidation over metal oxides

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Article information

DOI
https://doi.org/10.1039/C0CC00157K
Article type
Communication
Submitted
27 Feb 2010
Accepted
09 Apr 2010
First published
28 Apr 2010

Chem. Commun., 2010,46, 3991-3993

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Spin trapping of radical intermediates in gas phase catalysis: cyclohexane oxidation over metal oxides

M. Conte and V. Chechik, Chem. Commun., 2010, 46, 3991 DOI: 10.1039/C0CC00157K

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