Issue 27, 2010
From the journal:

Chemical Communications

Interaction of hydrogen with accessible metal sites in the metal–organic frameworks M2(dhtp) (CPO-27-M; M = Ni, Co, Mg)†

Pascal D. C. Dietzel,*a   Peter A. Georgiev,b   Juergen Eckert,c   Richard Blom,a   Thierry Strässled  and  Tobias Unruhe  

* Corresponding authors

a SINTEF Materials and Chemistry, P.O. Box 124 Blindern, N-0314 Oslo, Norway
E-mail: pascal.dietzel@sintef.no
Fax: +47 22067350
Tel: +47 98243958

b Department of Structural Chemistry, University of Milan, 21 Via G. Venezian, I-20133 Milan, Italy
E-mail: pageorgiev@yahoo.co.uk

c Materials Research Laboratory, University of California, Santa Barbara, USA
E-mail: juergen@mrl.ucsb.edu
Fax: +1 805 893 8797
Tel: +1 805 893 8247

d Laboratory for Neutron Scattering, ETH Zurich & Paul Scherrer Institut, 5232 Villigen PSI, Switzerland
E-mail: thierry.straessle@psi.ch

e FRM-II, Technische Universität München, 84748 Garching, Germany
E-mail: tobias.unruh@frm2.tum.de

Abstract

Hydrogen molecules adsorbed in the nickel, cobalt, and magnesium analogs of the CPO-27 metal–organic framework at low loadings interact significantly more strongly than those adsorbed successively as a consequence of the strong interaction of hydrogen with the coordinatively unsaturated metal cations in the framework.

Graphical abstract: Interaction of hydrogen with accessible metal sites in the metal–organic frameworks M2(dhtp) (CPO-27-M; M = Ni, Co, Mg)

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Article information

DOI
https://doi.org/10.1039/C0CC00091D
Article type
Communication
Submitted
23 Feb 2010
Accepted
06 May 2010
First published
28 May 2010

Chem. Commun., 2010,46, 4962-4964

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Interaction of hydrogen with accessible metal sites in the metal–organic frameworks M2(dhtp) (CPO-27-M; M = Ni, Co, Mg)

P. D. C. Dietzel, P. A. Georgiev, J. Eckert, R. Blom, T. Strässle and T. Unruh, Chem. Commun., 2010, 46, 4962 DOI: 10.1039/C0CC00091D

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