Issue 21, 2010
From the journal:

Chemical Communications

5-Hydroxy-2,2,6,6-tetramethyl-4-(2-methylprop-1-en-yl)cyclohex-4-ene-1,3-dione, a novel cheletropic trap for nitric oxide EPR detection†

Robert Lauricella,a   Mathilde Triquigneaux,a   Christiane André-Barrès,b   Laurence Charlesa  and  Béatrice Tuccio*a  

* Corresponding authors

a Laboratoire Chimie Provence, Equipe SACS, Aix-Marseille Université-CNRS-UMR 6264, 13397 Marseille Cedex 20, France
E-mail: beatrice.tuccio-lauricella@univ-provence.fr
Fax: +33 491 288 678
Tel: +33 491 288 743

b Laboratoire SPCMIB, Université Paul Sabatier-CNRS-UMR 5068, 31062 Toulouse Cedex, France

Abstract

The title compound behaves as an efficient cheletropic trap for both NO and NO2 radicals in the presence of oxygen, yielding EPR observable nitroxide and alkoxynitroxide, respectively.

Graphical abstract: 5-Hydroxy-2,2,6,6-tetramethyl-4-(2-methylprop-1-en-yl)cyclohex-4-ene-1,3-dione, a novel cheletropic trap for nitric oxide EPR detection

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Article information

DOI
https://doi.org/10.1039/C002990D
Article type
Communication
Submitted
11 Feb 2010
Accepted
10 Apr 2010
First published
21 Apr 2010

Chem. Commun., 2010,46, 3675-3677

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5-Hydroxy-2,2,6,6-tetramethyl-4-(2-methylprop-1-en-yl)cyclohex-4-ene-1,3-dione, a novel cheletropic trap for nitric oxide EPR detection

R. Lauricella, M. Triquigneaux, C. André-Barrès, L. Charles and B. Tuccio, Chem. Commun., 2010, 46, 3675 DOI: 10.1039/C002990D

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