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Issue 16, 2010
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Cooperative multimetallic catalysis using metallosalens

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Abstract

Metallosalen complexes are able to catalyze several transformations via a bimetallic, cooperative pathway. Various strategies to induce simultaneous activation by two metal centers with multinuclear catalysts have been reported to date, leading to higher reaction rates and selectivities in existing reactions. In some cases, new reactions could be realized that were previously not possible. The design principles, the most successful approaches and the catalytic applications of multinuclear metallosalen catalysts are discussed in this feature article.

Graphical abstract: Cooperative multimetallic catalysis using metallosalens

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Article information


Submitted
21 Jan 2010
Accepted
26 Feb 2010
First published
22 Mar 2010

Chem. Commun., 2010,46, 2713-2723
Article type
Feature Article

Cooperative multimetallic catalysis using metallosalens

R. M. Haak, S. J. Wezenberg and A. W. Kleij, Chem. Commun., 2010, 46, 2713
DOI: 10.1039/C001392G

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