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Issue 17, 2010
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Living catalyzed-chain-growthpolymerization and block copolymerization of isoprene by rare-earth metal allyl precursors bearing a constrained-geometry-conformation ligand

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Abstract

Aminophenyl functionalized cyclopentadienyl ligated rare-earth metal allyl mediated cationic systems display high cis-1,4 selectivity for the polymerization of isoprene, and living reversible and rapid chain transfer to aluminium additives.

Graphical abstract: Living catalyzed-chain-growth polymerization and block copolymerization of isoprene by rare-earth metal allyl precursors bearing a constrained-geometry-conformation ligand

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Article information


Submitted
21 Dec 2009
Accepted
01 Mar 2010
First published
25 Mar 2010

Chem. Commun., 2010,46, 3022-3024
Article type
Communication

Living catalyzed-chain-growth polymerization and block copolymerization of isoprene by rare-earth metal allyl precursors bearing a constrained-geometry-conformation ligand

Z. Jian, D. Cui, Z. Hou and X. Li, Chem. Commun., 2010, 46, 3022
DOI: 10.1039/B926813H

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