Issue 12, 2010
From the journal:

Chemical Communications

Synthesis and reactions of hydroxobis(η5-pentamethylcyclopenta-dienyl)(trifluoroethenyl)titanium(iv)†

Rainer Kickbuscha  and  Dieter Lentz*a  

* Corresponding authors

a Institut für Chemie und Biochemie – Anorganische Chemie, Freie Universität Berlin, Fabeckstr. 34-36, D-14195 Berlin, Germany
E-mail: lentz@chemie.fu-berlin.de
Fax: +49 30 83853310
Tel: +49 30 83852695

Abstract

Hydrolysis of the trifluoroethenyl titanium complexes 1a and b yields the hydroxo complexes 2 which can be deprotonated forming the sodium salt of the anionic oxo complex 4. 4a is one of the rare examples of monomeric organometallic anionic oxo complexes.

Graphical abstract: Synthesis and reactions of hydroxobis(η5-pentamethylcyclopenta-dienyl)(trifluoroethenyl)titanium(iv)

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Article information

DOI
https://doi.org/10.1039/B925655E
Article type
Communication
Submitted
08 Dec 2009
Accepted
27 Jan 2010
First published
15 Feb 2010

Chem. Commun., 2010,46, 2118-2120

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Synthesis and reactions of hydroxobis(η5-pentamethylcyclopenta-dienyl)(trifluoroethenyl)titanium(IV)

R. Kickbusch and D. Lentz, Chem. Commun., 2010, 46, 2118 DOI: 10.1039/B925655E

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