Issue 19, 2010
From the journal:

Chemical Communications

Atom-efficient synthesis of α-alkylidene-N-furylimines viacatalyticvinylcarbene-transfer reactions to carbonyl-ene-nitrile compounds†

Masahito Murai,a   Shotaro Yoshida,a   Koji Mikia  and  Kouichi Ohe*a  

* Corresponding authors

a Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan
E-mail: ohe@scl. kyoto-u.ac.jp
Fax: (+81) 75-383-2499
Tel: (+81) 75-383-2495

Abstract

The reaction of carbonyl-ene-nitrile compounds with propargyl carboxylates in the presence of a catalytic amount of PtCl2 afforded the α-alkylidene-N-furylimines with high stereoselectivities.

Graphical abstract: Atom-efficient synthesis of α-alkylidene-N-furylimines via catalytic vinylcarbene-transfer reactions to carbonyl-ene-nitrile compounds

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Article information

DOI
https://doi.org/10.1039/B924752A
Article type
Communication
Submitted
24 Nov 2009
Accepted
25 Feb 2010
First published
23 Mar 2010

Chem. Commun., 2010,46, 3366-3368

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Atom-efficient synthesis of α-alkylidene-N-furylimines via catalytic vinylcarbene-transfer reactions to carbonyl-ene-nitrile compounds

M. Murai, S. Yoshida, K. Miki and K. Ohe, Chem. Commun., 2010, 46, 3366 DOI: 10.1039/B924752A

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