Issue 11, 2010
From the journal:

Chemical Communications

α-Functionalization of non-activated aliphatic amines: ruthenium-catalyzed alkynylations and alkylations†

Irina Jovel,a   Saisuree Prateeptongkum,a   Ralf Jackstell,a   Nadine Vogl,b   Christoph Weckbeckerb  and  Matthias Beller*a  

* Corresponding authors

a Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany
E-mail: matthias.beller@catalysis.de
Fax: +49-381-1281-51113

b Evonik Degussa GmbH, Health and Nutrition, Rodenbacher Chaussee 4, 63457 Hanau, Germany

Abstract

Novel catalytic α-functionalizations of non-activated aliphatic amines with silylated alkynes are reported. In the presence of the Shvo catalyst alkylations and alkynylations proceed highly selectively to the branched amines.

Graphical abstract: α-Functionalization of non-activated aliphatic amines: ruthenium-catalyzed alkynylations and alkylations

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Article information

DOI
https://doi.org/10.1039/B924674F
Article type
Communication
Submitted
24 Nov 2009
Accepted
22 Dec 2009
First published
14 Jan 2010

Chem. Commun., 2010,46, 1956-1958

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α-Functionalization of non-activated aliphatic amines: ruthenium-catalyzed alkynylations and alkylations

I. Jovel, S. Prateeptongkum, R. Jackstell, N. Vogl, C. Weckbecker and M. Beller, Chem. Commun., 2010, 46, 1956 DOI: 10.1039/B924674F

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