Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 22nd May 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 16, 2010
Previous Article Next Article

Solvent-free microwave-assisted peroxidative oxidation of secondary alcohols to the corresponding ketones catalyzed by copper(II) 2,4-alkoxy-1,3,5-triazapentadienato complexes

Author affiliations

Abstract

A facile, efficient and selective solvent-free synthesis of ketones from secondary alcohols with tert-butylhydroperoxide (TBHP) as the oxidant under microwave irradiation is achieved, where the copper(II) 2,4-alkoxy-1,3,5-triazapentadienato complexes are efficient catalysts providing high yields (up to 100%), TONs (up to 890) and TOFs (up to 1780 h−1).

Graphical abstract: Solvent-free microwave-assisted peroxidative oxidation of secondary alcohols to the corresponding ketones catalyzed by copper(ii) 2,4-alkoxy-1,3,5-triazapentadienato complexes

Back to tab navigation

Supplementary files

Publication details

The article was received on 30 Oct 2009, accepted on 09 Feb 2010 and first published on 25 Feb 2010


Article type: Communication
DOI: 10.1039/B922738E
Chem. Commun., 2010,46, 2766-2768

  •   Request permissions

    Solvent-free microwave-assisted peroxidative oxidation of secondary alcohols to the corresponding ketones catalyzed by copper(II) 2,4-alkoxy-1,3,5-triazapentadienato complexes

    P. J. Figiel, M. N. Kopylovich, J. Lasri, M. F. C. G. da Silva, J. J. R. F. da Silva and A. J. L. Pombeiro, Chem. Commun., 2010, 46, 2766
    DOI: 10.1039/B922738E

Search articles by author

Spotlight

Advertisements