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Issue 9, 2010
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Facile access to internally functionalized dendrimers through efficient and orthogonal click reactions

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Abstract

A simple synthetic strategy has been developed for accessing internally functionalized dendrimers. The key feature of this approach is the use of two orthogonal and efficient reactions—‘epoxy–amine’ and ‘thiolene’ coupling—for rapid growth of the dendritic scaffold. This sequence of reactions allows for the introduction of reactive hydroxyl groups at each dendritic layer.

Graphical abstract: Facile access to internally functionalized dendrimers through efficient and orthogonal click reactions

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Supplementary files

Article information


Submitted
15 Oct 2009
Accepted
14 Jan 2010
First published
28 Jan 2010

Chem. Commun., 2010,46, 1556-1558
Article type
Communication

Facile access to internally functionalized dendrimers through efficient and orthogonal click reactions

T. Kang, R. J. Amir, A. Khan, K. Ohshimizu, J. N. Hunt, K. Sivanandan, M. I. Montañez, M. Malkoch, M. Ueda and C. J. Hawker, Chem. Commun., 2010, 46, 1556 DOI: 10.1039/B921598K

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