Issue 11, 2010
From the journal:

Chemical Communications

The cascade carbo-carbonylation of unactivated alkenes catalyzed by an organocatalyst and a transition metal catalyst: a facile approach to γ-diketones and γ-carbonyl aldehydes from arylalkenes under air†

Jin Xiea  and  Zhi-Zhen Huang*ab  

* Corresponding authors

a Key Laboratory of Mesoscopic Chemistry of MOE, College of Chemistry and Chemical Engineering, Nanjing University, Nanjing, P.R.China
E-mail: huangzz@nju.edu.cn

b State Key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin, P. R. China

Abstract

A novel cascade carbo-carbonylation reaction of unactivated arylalkenes with ketones or aldehydes was catalyzed by an organocatalyst and a transition metal catalystvia a SOMO-enamine under air, affording a simple approach to γ-diketones and γ-carbonyl aldehydes.

Graphical abstract: The cascade carbo-carbonylation of unactivated alkenes catalyzed by an organocatalyst and a transition metal catalyst: a facile approach to γ-diketones and γ-carbonyl aldehydes from arylalkenes under air

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Article information

DOI
https://doi.org/10.1039/B921310D
Article type
Communication
Submitted
13 Oct 2009
Accepted
14 Dec 2009
First published
13 Jan 2010

Chem. Commun., 2010,46, 1947-1949

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The cascade carbo-carbonylation of unactivated alkenes catalyzed by an organocatalyst and a transition metal catalyst: a facile approach to γ-diketones and γ-carbonyl aldehydes from arylalkenes under air

J. Xie and Z. Huang, Chem. Commun., 2010, 46, 1947 DOI: 10.1039/B921310D

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