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Issue 8, 2010
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An unusual case of symmetry-preserving isomerism

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Abstract

Two isomeric phases of the NbO-type structure have been discovered: PCN-16 (α phase) and PCN-16′ (β phase), and gas sorption studies revealed that the α phase possesses a larger surface area, leading to higher hydrogen and methane storage capacity as compared with the β phase.

Graphical abstract: An unusual case of symmetry-preserving isomerism

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Publication details

The article was received on 08 Oct 2009, accepted on 01 Dec 2009 and first published on 11 Jan 2010


Article type: Communication
DOI: 10.1039/B920995F
Chem. Commun., 2010,46, 1329-1331

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    An unusual case of symmetry-preserving isomerism

    D. Sun, S. Ma, J. M. Simmons, J. Li, D. Yuan and H. Zhou, Chem. Commun., 2010, 46, 1329
    DOI: 10.1039/B920995F

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