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Issue 4, 2010
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Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides

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Abstract

An unprecedented copper-catalysed allylic transposition enables the regioselective synthesis of branched allylic silanes from linear allylic halides through direct C–Si bond formation.

Graphical abstract: Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides

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Article information


Submitted
07 Oct 2009
Accepted
25 Nov 2009
First published
11 Dec 2009

Chem. Commun., 2010,46, 568-570
Article type
Communication

Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides

D. J. Vyas and M. Oestreich, Chem. Commun., 2010, 46, 568
DOI: 10.1039/B920793G

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