Issue 4, 2010

Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides

Abstract

An unprecedented copper-catalysed allylic transposition enables the regioselective synthesis of branched allylic silanes from linear allylic halides through direct C–Si bond formation.

Graphical abstract: Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides

Supplementary files

Article information

Article type
Communication
Submitted
07 Oct 2009
Accepted
25 Nov 2009
First published
11 Dec 2009

Chem. Commun., 2010,46, 568-570

Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides

D. J. Vyas and M. Oestreich, Chem. Commun., 2010, 46, 568 DOI: 10.1039/B920793G

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