Single and double substrate insertion into the TiNα bonds of terminal titanium hydrazides

Pei-Jen Tiong; A. Daniel Schofield; Jonathan D. Selby; Ainara Nova; Eric Clot; Philip Mountford

doi:10.1039/B920090H

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Single and double substrate insertion into the TiN_α bonds of terminal titanium hydrazides†

Pei-Jen Tiong,^a A. Daniel Schofield,^a Jonathan D. Selby,^a Ainara Nova,^b Eric Clot*^b and Philip Mountford*^a

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* Corresponding authors

^a Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford, UK
E-mail: philip.mountford@chem.ox.ac.uk

^b Institut Charles Gerhardt Montpellier, CNRS 5253, Université Montpellier 2, cc 1501, Place Eugène Bataillon, F-34095 Montpellier Cedex 5, France
E-mail: eric.clot@univ-montp2.fr

Abstract

Nitriles, CO₂ and isocyanates undergo net single or double insertion reactions into the Ti [double bond, length as m-dash] N_α multiple bonds of terminal titanium hydrazides. These are the first such examples of this type of reactivity for any transition metal hydrazide complex.

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Article information

DOI: https://doi.org/10.1039/B920090H
Article type: Communication
Submitted: 28 Sep 2009
Accepted: 02 Nov 2009
First published: 19 Nov 2009

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Chem. Commun., 2010,46, 85-87

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Single and double substrate insertion into the TiN_α bonds of terminal titanium hydrazides

P. Tiong, A. D. Schofield, J. D. Selby, A. Nova, E. Clot and P. Mountford, Chem. Commun., 2010, 46, 85 DOI: 10.1039/B920090H

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