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Issue 6, 2010
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Gold(I)-catalysed cycloisomerisation of 1,6-enynes into functionalised allenes

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Abstract

1,6-Enynes can be transformed into vinylidenecyclopentanes via gold-promoted 5-exo dig cyclisation followed by 1,5-hydride or -alkoxide shift.

Graphical abstract: Gold(i)-catalysed cycloisomerisation of 1,6-enynes into functionalised allenes

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Publication details

The article was received on 16 Sep 2009, accepted on 17 Dec 2009 and first published on 07 Jan 2010


Article type: Communication
DOI: 10.1039/B919240A
Citation: Chem. Commun., 2010,46, 865-867
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    Gold(I)-catalysed cycloisomerisation of 1,6-enynes into functionalised allenes

    Y. Harrak, A. Simonneau, M. Malacria, V. Gandon and L. Fensterbank, Chem. Commun., 2010, 46, 865
    DOI: 10.1039/B919240A

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