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Issue 8, 2010
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Activation of H2 by a highly distorted RhII complex with a new C3-symmetric tripodal tetraphosphine ligand

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Abstract

Facile oxidation of a sterically encumbered RhI complex generates a stable RhII metalloradical species; the latter is able to activate H2 under formation of the corresponding RhIII complex.

Graphical abstract: Activation of H2 by a highly distorted RhII complex with a new C3-symmetric tripodal tetraphosphine ligand

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Article information


Submitted
26 Aug 2009
Accepted
17 Dec 2009
First published
12 Jan 2010

Chem. Commun., 2010,46, 1232-1234
Article type
Communication

Activation of H2 by a highly distorted RhII complex with a new C3-symmetric tripodal tetraphosphine ligand

J. Wassenaar, B. de Bruin, M. A. Siegler, A. L. Spek, J. N. H. Reek and J. I. van der Vlugt, Chem. Commun., 2010, 46, 1232
DOI: 10.1039/B917632B

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