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Issue 8, 2010
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Thermo-responsive microphase separated supramolecular polyurethanes

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Abstract

The ability to generate very stable assemblies via non-covalent interactions has enabled materials to be constructed that were not feasible via ‘traditional’ covalent bond formation processes. A series of low molecular mass bisurethane and bisurea polymers have been developed that form stable self-assembled networks through hydrogen bonding interactions. Thermo-responsive polymers were generated by end-capping poly(ethylene-co-butylene) or polybutadiene chains with the bisurethane or bisurea motif. Microphase separation is observed via TEM and small-angle X-ray scattering (SAXS) for the modified pseudo polymers and significant differences in the temperature dependence of microphase separation are analysed via SAXS. The importance of the polarity of the end groups is manifested in distinct temperature-dependent microphase separation behaviour. Information on the local hydrogen bonding structure is provided by wide-angle X-ray scattering and variable temperature FTIR.

Graphical abstract: Thermo-responsive microphase separated supramolecular polyurethanes

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Publication details

The article was received on 20 Apr 2010, accepted on 07 Jun 2010 and first published on 05 Jul 2010


Article type: Paper
DOI: 10.1039/C0PY00122H
Polym. Chem., 2010,1, 1263-1271

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    Thermo-responsive microphase separated supramolecular polyurethanes

    D. H. Merino, A. T. Slark, H. M. Colquhoun, W. Hayes and I. W. Hamley, Polym. Chem., 2010, 1, 1263
    DOI: 10.1039/C0PY00122H

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