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Issue 6, 2010
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Metal catalysts for ε-caprolactonepolymerisation†

Abdessamad Arbaouia  and  Carl Redshaw*a  
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* Corresponding authors

a Energy Materials Laboratory, School of Chemistry, University of East Anglia, Norwich, UK
E-mail: carl.redshaw@uea.ac.uk
Fax: +44 (0) 1603 592003
Tel: +44 (0) 1603 593137

Abstract

Economic pressure, environmental issues and ever increasing demand are driving the shift from oil-based polymers to those available from renewable resources. Ring opening polymerisation of cyclic esters is currently a topical field with metal complex-induced coordination/insertion type polymerisation leading the way. Such a polymerisation method offers a wide range of advantages from control over the polymer structure to kinetic enhancement; however industrially available catalysts based on tin suffer from inherent toxicity and as a result a policy change from the Food and Drug Administration (FDA) is not unrealistic. This review underlines the efforts made in the past five years or so, and shows how low toxicity metals are attracting increasing attention in the field of ε-caprolactone polymerisation.

Graphical abstract: Metal catalysts for ε-caprolactone polymerisation

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Article information

https://doi.org/10.1039/B9PY00334G
Submitted
02 Nov 2009
Accepted
08 Dec 2009
First published
13 Jan 2010
Polym. Chem., 2010,1, 801-826
Article type
Review Article
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Metal catalysts for ε-caprolactone polymerisation

A. Arbaoui and C. Redshaw, Polym. Chem., 2010, 1, 801
DOI: 10.1039/B9PY00334G

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