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Issue 20, 2010
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Organosilicon-mediated total synthesis of the triquinane sesquiterpenes (±)-β-isocomene and (±)-isocomene

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Abstract

We describe an efficient total synthesis of the sesquiterpenes (±)-β-isocomene and (±)-isocomene using a Lewis acid-promoted [3 + 2] cycloaddition of allyl-tert-butyldiphenylsilane as the key-step.

Graphical abstract: Organosilicon-mediated total synthesis of the triquinane sesquiterpenes (±)-β-isocomene and (±)-isocomene

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Publication details

The article was received on 27 Apr 2010, accepted on 05 Jul 2010 and first published on 28 Jul 2010


Article type: Paper
DOI: 10.1039/C0OB00051E
Citation: Org. Biomol. Chem., 2010,8, 4562-4568

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    Organosilicon-mediated total synthesis of the triquinane sesquiterpenes (±)-β-isocomene and (±)-isocomene

    A. W. Schmidt, T. Olpp, E. Baum, T. Stiffel and H. Knölker, Org. Biomol. Chem., 2010, 8, 4562
    DOI: 10.1039/C0OB00051E

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