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Issue 8, 2010
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Synthesis, structures and properties of biferrocenyl- and ruthenocenyl-substituted diphosphenes†‡

Takahiro Sasamori,*a   Akimi Hori,a   Yoshikazu Kanekoa  and  Norihiro Tokitoh*a  
Author affiliations

* Corresponding authors

a Institute for Chemical Research, Kyoto University, Gokasho, Uji, Japan
E-mail: tokitoh@boc.kuicr.kyoto-u.ac.jp, sasamori@boc.kuicr.kyoto-u.ac.jp
Fax: +81 774-38-3209
Tel: +81 774-38-3200

Abstract

Biferrocenyl and ruthenocenyl diphosphenes were synthesized in a stable crystalline form as new members of a family of d-π systems containing heavier main group elements. Their structures and redox behavior were revealed using X-ray crystallographic analysis and cyclic voltammetry.

Graphical abstract: Synthesis, structures and properties of biferrocenyl- and ruthenocenyl-substituted diphosphenes

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Article information

https://doi.org/10.1039/C0NJ00062K
Submitted
26 Jan 2010
Accepted
06 Apr 2010
First published
22 Apr 2010
New J. Chem., 2010,34, 1560-1564
Article type
Letter
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Synthesis, structures and properties of biferrocenyl- and ruthenocenyl-substituted diphosphenes

T. Sasamori, A. Hori, Y. Kaneko and N. Tokitoh, New J. Chem., 2010, 34, 1560
DOI: 10.1039/C0NJ00062K

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