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Issue 4, 2010
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TUD-1: synthesis and application of a versatile catalyst, carrier, material…

Selvedin Telalović,a   Anand Ramanathan,b   Guido Mula  and  Ulf Hanefeld*a  
Author affiliations

* Corresponding authors

a Gebouw voor Scheikunde, Technische Universiteit Delft, Julianalaan 136, 2628 BL Delft, The Netherlands
E-mail: u.hanefeld@tudelft.nl
Fax: +31 15 278 1415
Tel: +31 15 278 9304

b Department of Chemistry, University College of Engineering, Tindivanam (Anna University, Chennai), Saram–604307, Tamil Nadu, India
E-mail: anand_ncl@yahoo.com

Abstract

The three-dimensional sponge-like mesoporous material TUD-1 is straightforward to prepare. Its synthesis can readily be modified to introduce metals into the framework of TUD-1, imparting many different catalytic activities. M-TUD-1 catalysts have proven to be very active, unlimited by diffusion and very stable. By combining two metals into one TUD-1 catalyst, synergy between Lewis and Brønsted acid sites could be induced; incorporation of zeolites similarly gave rise to synergy. In addition to successful applications in redox-, acid- and photo-catalysis TUD-1 proved to be an excellent carrier material for catalysts, enabling new applications. TUD-1 was used as a contrast agent and drug delivery system, indicating that this material is but at the beginning of its potential applications.

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Article information

https://doi.org/10.1039/B904193A
Submitted
02 Mar 2009
Accepted
30 Jul 2009
First published
28 Aug 2009
This article is Open Access
J. Mater. Chem., 2010,20, 642-658
Article type
Feature Article
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TUD-1: synthesis and application of a versatile catalyst, carrier, material…

S. Telalović, A. Ramanathan, G. Mul and U. Hanefeld, J. Mater. Chem., 2010, 20, 642
DOI: 10.1039/B904193A

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