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Issue 10, 2010
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Preparation and application of SBA-15-supported palladium catalyst for Suzuki reaction in supercritical carbon dioxide

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Abstract

The external and internal surfaces of SBA-15 were modified by (MeO)3SiPh and a phosphine ligand, (MeO)3SiCH2CH2CH2SCH2C6H4PPh2, before and after the template Pluronic P123 copolymer was removed, respectively. Palladium was then tethered within the cavity of the mesoporous material Ph-SBA-15-PPh3via a ligand-exchange reaction to provide a new supported palladium catalyst Ph-SBA-15-PPh3-Pd. This catalyst was demonstrated to be a robust and active catalyst in Suzuki reaction of a wide range of aryl bromides with arylboronic acids in supercritical carbon dioxide. After the reaction mixtures were treated at 90 °C for 24 h, the crude coupling products were obtained as crystalline solids when the reaction temperature was lowered to room temperature and the carbon dioxide was then slowly released. The pure products can be obtained by simple recrystallization in good to excellent yields. The Ph-SBA-15-PPh3-Pd catalyst has low leaching loss and can be reused at least 7 times without loss of activity.

Graphical abstract: Preparation and application of SBA-15-supported palladium catalyst for Suzuki reaction in supercritical carbon dioxide

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Article information


Submitted
15 Mar 2010
Accepted
11 Aug 2010
First published
13 Sep 2010

Green Chem., 2010,12, 1758-1766
Article type
Paper

Preparation and application of SBA-15-supported palladium catalyst for Suzuki reaction in supercritical carbon dioxide

X. Feng, M. Yan, T. Zhang, Y. Liu and M. Bao, Green Chem., 2010, 12, 1758
DOI: 10.1039/C004250A

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