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Issue 35, 2010
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Diverse reactions of sterically-protected 1,3-diphosphacyclobutane-2,4-diyls with hydride

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Abstract

Hydride-induced elimination of resonance stabilized substituents from a phosphorus center of 1,3-diphosphacyclobutane-2,4-diyls leads to the formation of versatile cyclic phosphaallyl anions that are useful for the construction of various electrophile-modified biradical species.

Graphical abstract: Diverse reactions of sterically-protected 1,3-diphosphacyclobutane-2,4-diyls with hydride

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Article information


Submitted
24 May 2010
Accepted
15 Jun 2010
First published
05 Aug 2010

Dalton Trans., 2010,39, 8281-8287
Article type
Paper

Diverse reactions of sterically-protected 1,3-diphosphacyclobutane-2,4-diyls with hydride

S. Ito, J. Miura, N. Morita, M. Yoshifuji and A. J. Arduengo III, Dalton Trans., 2010, 39, 8281
DOI: 10.1039/C0DT00532K

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